The asynchronous capacity region of a memoryless multiple-access channel is the union of certain polytopes henceforth called rate regions. Each rate region has a dominant face and it is well-known that vertices of the dominant face may be approached via a technique called successive decoding. It is also known that an extension of successive decoding applies to all points that are on the boundary of the dominant face. The extension consists of forming groups of users in such a way that users within a group can be decoded jointly whereas groups are decoded successively. It is insightful to obtain these and new results as a straightforward consequence the structure of the rate regions. The focus of our presentation is on that structure. In particular, we show how an arbitrary face of a rate region decomposes into the Cartesian product of one or more lower-dimensional dominant faces and at most one rate region.